Heterogeneous catalytic synthesis and structure of 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline

Hydrogenation of 10 H-indeno[1,2-b]quinoline in benzene in the presence of R2S7 {Mathematical expression} gave 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline, the structure of which was established by mass-, IR, UV,13C, and1H NMR spectra. The cis fusion of the indan and tetrahydroquinoline fragments, the axial orientation of the proton at C(5a), and the equatorial orientation of the proton at C(10a) were confirmed by molecular mechanics calculations using the PC MODEL program. © 1995 Plenum Publishing Corporation.

Авторы
Редакторы
-
Издательство
-
Номер выпуска
6
Язык
Английский
Страницы
1037-1040
Статус
Опубликовано
Подразделение
-
Номер
-
Том
43
Год
1994
Организации
  • 1 Russian People's Friendship University, 6 ul. Miklucho-Maklaya, Moscow, 117198, Russian Federation
  • 2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow, 117913, Russian Federation
Ключевые слова
10 H-indeno[1,2-b]quinoline, hydrogenation; 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline, stereochemistry; molecular mechanics calculations, PC MODEL program; rhenium heptasulfide
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/942/