Heterogeneous catalytic synthesis and structure of 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline

Hydrogenation of 10 H-indeno[1,2-b]quinoline in benzene in the presence of R2S7 {Mathematical expression} gave 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline, the structure of which was established by mass-, IR, UV,13C, and1H NMR spectra. The cis fusion of the indan and tetrahydroquinoline fragments, the axial orientation of the proton at C(5a), and the equatorial orientation of the proton at C(10a) were confirmed by molecular mechanics calculations using the PC MODEL program. © 1995 Plenum Publishing Corporation.

Authors
Number of issue
6
Language
English
Pages
1037-1040
Status
Published
Volume
43
Year
1994
Organizations
  • 1 Russian People's Friendship University, 6 ul. Miklucho-Maklaya, Moscow, 117198, Russian Federation
  • 2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow, 117913, Russian Federation
Keywords
10 H-indeno[1,2-b]quinoline, hydrogenation; 5,5a,10a,11-tetrahydro-10 H-indeno[1,2-b]quinoline, stereochemistry; molecular mechanics calculations, PC MODEL program; rhenium heptasulfide
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/942/