Synthesis, structure, and magnetic properties of bis(1-amino-9-hydroxy-4- azafluorenium) hexachlorocuprate(II) Cu2Cl6(C 12H11N2O)2

The complex Cu2Cl6(C12H11N 2O)2 was synthesized by reacting copper(II) chloride crystal hydrate with 1-amino-9-hydroxy-4-azafluorene, and its crystal structure was determined. Cu2Cl6(C12H11N 2O)2 is a centrosymmetric dimer with chlorine bridges, in which the organic ligand is coordinated to the copper atom through the oxygen atom of the hydroxyl group. The CuCl4O polyhedron is a distorted tetragonal pyramid in which the oxygen atom is in the axial position. In crystal, dimers are linked by hydrogen bonds to form a three-dimensional framework. The complex exhibits ferromagnetic properties, as was shown by EPR.

Авторы
Kuz'mina N.E.1 , Palkina K.K.1 , Polyakova N.V. 2 , Golubev I.N.3 , Medvedev A.N.3 , Koval'chukova O.V. 2 , Strashnova S.B. 2 , Zaitsev B.E. 2 , Levov A.N. 2 , Toze F. 2
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
11
Язык
Английский
Страницы
1693-1697
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
47
Год
2002
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 11991, Russian Federation
  • 2 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Russ. Res. Inst. Organ. Chem. T., sh. Entuziastov 23, Moscow, 111024, Russian Federation
Ключевые слова
1 amino 9 hydroxy 4 azafluorene; bis(1 amino 9 hydroxy 4 azafluorenium)hexachlorocuprate; chlorine; copper; copper chloride; copper derivative; dimer; ferromagnetic material; fluorene derivative; hydrogen; hydroxyl group; ligand; organic compound; oxygen; unclassified drug; article; atom; crystal; crystal structure; drug structure; drug synthesis; electron spin resonance; hydrogen bond; magnetism; reaction analysis
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/252/