Effect of the nature of axial ligand on the effective charge of the metal center in PcFe(II) complexes

Disubstituted iron phthalocyanine complexes were studied by X-ray photoelectron spectroscopy (XPS). Fe2p 3/2, N1s, and C1s XPS spectra were analyzed, and the role of the ligand in their generation was determined. Assignment of the magnetic properties of phthalocyanine iron complexes was done. Covalence of the metal-ligand bond was determined. The nature of the axial ligand in PctFe affects the electronic state of the central iron atom. © 2008 Pleiades Publishing, Ltd.

Авторы
Ivanova T.M. 1 , Linko R.V. 2 , Petrov A.V.3 , Bazanov M.I.3 , Dyumaev K.M.4
Журнал
Russian Journal of Inorganic Chemistry
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
11
Язык
Английский
Страницы
1784-1787
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1134/S0036023608110193
Том
53
Год
2008
Организации
  • 1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russian Federation
  • 2 Russian University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 3 Ivanovo State University of Chemical Technology, pr. Engelsa 7, Ivanovo 153460, Russian Federation
  • 4 All-Russia Institute of Medicinal and Aromatic Plants, Moscow, Russian Federation
Ключевые слова
Electronic states; Iron compounds; Ligands; Axial ligand; Effective charge; Iron atoms; Iron complex; Iron phthalocyanines; Metal centers; Metal-ligand bonds; XPS spectra; X ray photoelectron spectroscopy
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