Spin-vibrational interactions in geminate radical pairs: Effective spin hamiltonian including anharmonicity

An equation for the effective spin Hamiltonian including the interaction of radical pair spins with vibrations in both linear and higher approximations was obtained. Even in the linear approximation, the Hamiltonian was found to be non-Heisenberg. The influence of a sound field on the probability of geminate radical pair recombination is considered in the Appendix. The results obtained can be of use for solving certain nanochemistry problems. © 2008 Pleiades Publishing, Ltd.

Авторы
Kubarev S.I.1 , Shigaev A.S.2 , Kubareva I.S. 3 , Ponomarev V.O.4 , Ponomarev O.A.2
Редакторы
-
Издательство
-
Номер выпуска
3
Язык
Английский
Страницы
329-342
Статус
Опубликовано
Подразделение
-
Номер
-
Том
2
Год
2008
Организации
  • 1 Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 117977, Russian Federation
  • 2 Institute of Cell Biophysics, Russian Academy of Sciences, Pushchino, Moscow oblast, 142292, Russian Federation
  • 3 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 4 Moscow State Academy of Water Transport, Moscow, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3155/