Synthesis of epoxyoxirano- and epoxydihydroxyisoindolones

1-Oxo-3a,6-epoxyisoindolones oxidized with potassium permanganate to give 4,5-dihydroxy-3a,6-epoxyisoindolones, while oxidation with peroxyformic acid or 3-chloroperoxybenzoic acid yielded 2,6a-epoxyoxirano[e]isoindolones. Oxidation proceeded with selective formation of exo-cis-adducts. © 2012 Springer Science+Business Media New York.

Authors
Zubkov F.I. 1 , Zaytsev V.P. 1 , Airiyan I.K. 1 , Golubev V.D. 1 , Puzikova E.S. 1 , Sorokina E.A. 1 , Nikitina E.V. 1 , Varlamov A.V. 1
Journal
Russian Chemical Bulletin
Number of issue
3
Language
English
Pages
600-605
Status
Published
Link
External link
DOI
10.1007/s11172-012-0087-5
Volume
61
Year
2012
Organizations
  • 1 Peoples' Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation
Keywords
2,6a-epoxyoxirano[e]isoindolones; 3a,6-epoxyisoindoles; 4,5-dihydroxy-3a,6-epoxyisoindolones; the Prilezhaev reaction; the Wagner reaction
Date of creation
19.10.2018
Date of change
13.08.2021
Short link
https://repository.rudn.ru/en/records/article/record/2345/
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