The phenylation of 3βpicoline. Isolation and establishment of the structure of β-pyridyl-α-dehydropiperidine

It was established that the side product that is formed in substantial amounts in the phenylation of β-picoline by phenyllithium is 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperidyl-6)pyridine - a structural analog of anabasine. Its structure was demonstrated by spectral methods and by chemical conversions. © 1985 Plenum Publishing Corporation.

Authors
Prostakov N.S. 1 , Bu Habib H. , Rezakov V.A. 1 , Fomichev A.A. 1 , Kirillova L.M. 1 , Shevtsov V.K. 1
Journal
Chemistry of Heterocyclic Compounds
Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Number of issue
8
Language
English
Pages
911-915
Status
Published
Link
External link
DOI
10.1007/BF00513581
Volume
20
Year
1984
Organizations
  • 1 P. Lumumba Peoples' Friendship University, Moscow, 117923, Russian Federation
Cite
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MASS SPECTROMETRIC STUDY OF 9-SUBSTITUTED 10-SILA-2-AZAANTHRACENES

Article
Varlamov A.V., Shevtsov V.K., Klochkov A.M., Prostakov N.S.
Chemistry of Heterocyclic Compounds. Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau. Vol. 20. 1984. P. 869-874