Synthesis, Crystal Structure, and IR Spectra of catena-[trans-Dichloro-μ-spiro{cyclohexane-1′,3-[1-(4′,4′- dimethyl-2′,6′-dioxo-1′-cyclohexylidene)-1,2,3,4- tetrahydroisoquinoline-O,O]}copper(II)] Monohydrate

CuCl2 · nH2O (n < 2) reacts with spiro{cyclohexane-1′,3-[1-(4′,4′-dimethyl-2′,6′- dioxo-1′-cyclohexylidene)-1,2,3,4-tetrahydroisoquinoline]} (L1) in an acetone-heptane mixture to produce the complex [CuL1Cl2]n · nH2O (I). According to X-ray structural analysis, in the polymeric chain structure of I, L1 occurs as the enamine-diketone tautomer and acts as a bidentate bridging ligand, which coordinates copper via two oxygen atoms. The IR spectra of the complex are considered.

Авторы
Davydov V.V. 1 , Sokol V.I.2 , Balebanova E.V. 1 , Sergienko V.S.2 , Shklyaev Yu.V.3
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
5
Язык
Английский
Страницы
704-711
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
43
Год
1998
Организации
  • 1 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 2 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/691/