Synthesis and Structure of Copper(II) Chloride and Copper(II) Perchlorate Complexes with 3,3-Dimethyl-3,4-dihydroisocarbostyril: Crystal Structure of the [CuL2Cl2]2 Complex

Copper(II) chloride and copper(II) perchlorate crystal hydrates react with 3,3-dimethyl-3,4-dihydroisocarbostyril (L1) to produce [CuL1 2Cl2]2 and [CuL1 4 (ClO4)2], respectively. The [CuL1 2 Cl2]2 complex is characterized by X-ray crystallography. In contrast to the reactions of copper(II) salts with 3,3-dimethyl-3,4-dihydrothioisocarbostyril, the above reaction is not accompanied by reduction of Cu(II) to Cu(I). Both the free and coordinated ligand L1 occur in the lactam form. The ligand coordinates the metal through the oxygen atom. The IR spectra of the complexes are discussed, and molar conductivity of their solutions is measured.

Авторы
Sokol V.I.1 , Davydov V.V. 2 , Balebanova E.V. 2 , Sergienko V.S.1 , Shklyaev Yu.V.3 , Zaitsev B.E. 2
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
4
Язык
Английский
Страницы
485-491
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
43
Год
1998
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/690/