Synthesis, crystal structure, and spectra of bis(3,3-dimethyl-3,4-dihydroisocarbostyril)azinium nitrate

Bis(3,3-dimethyl-3,4-dihydroisocarbostyril)azinium nitrate (HL)NO3 (I) is synthesized, and its crystal structure is determined. It is shown that protonation of L proceeds at one of the exocyclic nitrogen atoms. The tautomeric form of the HL+ cation in I is intermediate between the azine and hydrazine tautometric forms. The structure of I is studied by IR and electronic absorption spectroscopies.

Авторы
Sokol V.I.1 , Ryabov M.A. 2 , Davydov V.V. 2 , Merkur'eva N.Yu. 2 , Shklyaev Yu.V.3 , Sergienko V.S.1 , Zaitsev B.E. 2
Редакторы
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Издательство
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Номер выпуска
5
Язык
Английский
Страницы
782-788
Статус
Опубликовано
Подразделение
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DOI
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Номер
-
Том
43
Год
1998
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/641/