Crystal and molecular structure of the mercury dichloride complex with the macrocyclic dibenzo-aza-14-crown-4 ether ligand containing the embedded Di(α-pyridyl)bispidone fragment, [Hg(L)Cl2]

The crystal and molecular structure of [Hg(L)Cl2] (I), where L is dibenzo-aza-14-crown-4 ether with the embedded di(α-pyridyl)bispidone fragment, is studied by X-ray diffraction. The irregular five-vertex polyhedron of the Hg atom is formed by two Cl atoms and three N atoms of the dipyridylbispidone part of the L molecule. The O and N atoms of the macrocycle are not involved in metal coordination. The structure of complex I is compared with the structures of compounds [Zn(L)Cl2]·C2H5OH, [Co(L)(H2O)][CoCl4], and [Cu(L)(H2O)](ClO4)·2H2O studied earlier. © Pleiades Publishing, Ltd., 2016.

Авторы
Polyakova I.N.1 , Sergienko V.S. 1 , Kvartalov V.B. 2 , Kolyadina N.M. 2 , Sokol V.I.1
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
2
Язык
Английский
Страницы
168-173
Статус
Опубликовано
Том
61
Год
2016
Организации
  • 1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University of Russia, Moscow, Russian Federation
Ключевые слова
Atoms; Crystal structure; Ethers; Molecular structure; X ray diffraction; Complex i; Crystal and molecular structure; Ether ligands; Five-vertex polyhedron; Macrocycles; Macrocyclics; Mercury dichloride; Metal coordination; Mercury compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/4014/