Mechanistic insights into the microwave-assisted cinnamyl alcohol oxidation using supported iron and palladium catalysts

The efficient oxidation of alcohols remains a challenge, especially when using solid heterogeneous catalysts. Herein, the catalytic activity of mechanochemically prepared iron and palladium particles on various supports are compared for the oxidation of cinnamyl alcohol to cinnamaldehyde and benzaldehyde in acetonitrile using aqueous hydrogen peroxide as the oxidant assisted by microwave irradiation. Important insights into the mechanism of the reaction towards the differently observed products have been provided. © 2019 Elsevier B.V.

Авторы
Wang Y.1 , Prinsen P.2 , Mangin F.1 , Yepez A.2 , Pineda A.2 , Rodríguez-Castellón E.3 , Hasan Shah Gilani M.R. , Xu G.5 , Len C.1, 6 , Luque R. 2, 5, 7
Журнал
Molecular Catalysis
Издательство
Elsevier B.V.
Язык
Английский
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1016/J.MCAT.2019.110409
Номер
110409
Год
2019
Организации
  • 1 Sorbonne Universités, Université de Technologie de Compiègne, Centre de Recherche Royallieu, CS 60319, Compiègne cedex, F-60203, France
  • 2 Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, km. 396, Cordoba, E-14014, Spain
  • 3 Departamento de Química Inorgánica, Cristalografía y Mineralogía (Unidad Asociada al ICP-CSIC), Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos, Málaga, 29071, Spain
  • 4 Department of Chemistry, Government College University of Faisalabad, Layyah campus, Layyah, Pakistan
  • 5 The State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China
  • 6 PSL Research University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 11 rue Pierre et Marie Curie, Paris Cedex 05, F-75231, France
  • 7 Peoples Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya str., Moscow, 117198, Russian Federation
Ключевые слова
Cinnamyl alcohol; Fe and Pd; Hydrogen peroxide; Microwave irradiation; Oxidation
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