Mechanistic insights into the microwave-assisted cinnamyl alcohol oxidation using supported iron and palladium catalysts

The efficient oxidation of alcohols remains a challenge, especially when using solid heterogeneous catalysts. Herein, the catalytic activity of mechanochemically prepared iron and palladium particles on various supports are compared for the oxidation of cinnamyl alcohol to cinnamaldehyde and benzaldehyde in acetonitrile using aqueous hydrogen peroxide as the oxidant assisted by microwave irradiation. Important insights into the mechanism of the reaction towards the differently observed products have been provided. © 2019 Elsevier B.V.

Authors
Wang Y.1 , Prinsen P.2 , Mangin F.1 , Yepez A.2 , Pineda A.2 , Rodríguez-Castellón E.3 , Hasan Shah Gilani M.R. , Xu G.5 , Len C.1, 6 , Luque R. 2, 5, 7
Journal
Molecular Catalysis
Publisher
Elsevier B.V.
Language
English
Status
Published
Link
External link
DOI
10.1016/j.mcat.2019.110409
Number
110409
Year
2019
Organizations
  • 1 Sorbonne Universités, Université de Technologie de Compiègne, Centre de Recherche Royallieu, CS 60319, Compiègne cedex, F-60203, France
  • 2 Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, km. 396, Cordoba, E-14014, Spain
  • 3 Departamento de Química Inorgánica, Cristalografía y Mineralogía (Unidad Asociada al ICP-CSIC), Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos, Málaga, 29071, Spain
  • 4 Department of Chemistry, Government College University of Faisalabad, Layyah campus, Layyah, Pakistan
  • 5 The State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China
  • 6 PSL Research University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 11 rue Pierre et Marie Curie, Paris Cedex 05, F-75231, France
  • 7 Peoples Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya str., Moscow, 117198, Russian Federation
Keywords
Cinnamyl alcohol; Fe and Pd; Hydrogen peroxide; Microwave irradiation; Oxidation
Date of creation
19.07.2019
Date of change
19.07.2019
Short link
https://repository.rudn.ru/en/records/article/record/38540/
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