Oxidizing reactions of azines. 7*. Imination of 4-aryl-1,2,3,6-tetrahydropyridines by arylamines in the presence of potassium permanganate. Molecular structure of 1-methyl-2-(4-nitrophenylimino)-4-phenyl-1,2,5,6-tetrahydropyridine

On treating 4-aryl substituted 1-methyl-1,2,3,6-tetrahydropyridines with potassium permanganate in the presence of arylamines a previously unknown intermolecular oxidative imination reaction occurs leading to the formation of 2-(arylimino)-1,2,5,6-tetrahydropyridines. The molecular structure of 1-methyl-2-(4-nitrophenylimino)-4-phenyl-1,2,5,6-tetrahydropyridine was studied by X-ray analysis and it was shown that the hydropyridine ring of the molecule has a sofa conformation and its amidine fragment is in the E-configuration.

Авторы
Soldatenkov A.T. 1 , Khristoforova T.P. 1 , Temesgen A.W. 1 , Anissimov B.N. 1 , Averkiev B.B.2 , Kuleshova L.N.2 , Khrustalev V.N.2 , Antipin M.Yu. 1
Редакторы
-
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
6
Язык
Английский
Страницы
715-722
Статус
Опубликовано
Подразделение
-
Номер
-
Том
37
Год
2001
Организации
  • 1 Russian Peoples' Friendship University, Moscow 117198, Russian Federation
  • 2 A. N. Nesmeyanov Institute of Organoelement Compounds, Moscow 117813, Russian Federation
Ключевые слова
Oxidative imination of 4-aryl-1,2,3,6-tetrahydropyridines
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/330/