Effect of low-temperature treatment on the state of gold hydrosol particles

A shift of the Plasmon absorption spectrum into the long-wave region, which increases with decreasing temperature and increasing duration of low-temperature treatment (LTT), was revealed after LTT at 217-77 K of Au hydrosol with a particle size of 10-11 nm. It was demonstrated that a decrease in the effective concentration of conduction electrons (Ne) after LTT is accompanied by an alteration in the damping coefficient of plasma resonance oscillations (y) and the volume fraction of Au particles (Nv). The temperature dependences of y and Nv, just as for silver sol, are stipulated by the tunnel mechanism of the formation of low- temperature defects in the presence of two-dimensionally mobile positively charged aqua complexes X+(H2O)?. A feature of Au sol was revealed: the maximum on dependences of y and Nv on the duration of LTT and the linear y-Ne correlation. © Pleiades Publishing, Ltd., 2010.

Номер выпуска
6
Язык
Английский
Страницы
1053-1058
Статус
Опубликовано
Том
84
Год
2010
Организации
  • 1 Russian Peoples' Friendship University, Moscow, 117198, Russian Federation
Ключевые слова
Aqua complexes; Au particles; Conduction electrons; Damping coefficients; Effective concentration; Gold hydrosols; Low temperatures; Plasma resonance; Positively charged; Temperature dependence; Silver; Sols; Absorption spectroscopy
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2767/
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