Complex compounds of Some p, d, and f metals with 2,4,6-Tris(N,N- dimethylaminomethyl)phenol (HL): Crystal and molecular structure of H 4L(NO3)3 · H2O and H 4LCl3 · 3H2O

Eight aluminum, cobalt(II), copper(II), cadmium, samarium(III), and europium(III) complexes with 2,4,6-tris(N,N-dimethylaminomethyl)phenol (HL) were isolated in the crystalline state and studied by physicochemical methods (IR and UV-Vis spectroscopy, potentiometry). The complexation processes of sin- gly, doubly, and triply charged metal ions with HL were studied by spectrophotometry and potentiometry, the composition of complexes was determined, and the stability constants were calculated. The crystal and molecular structures of 2,4,6-tris(N,N-dimethylaminomethyl)phenol trichloride and trinitrate H 4L(NO3)3 · H2O and H 4LCl3 · 3H2O were studied by X-ray diffraction. © Pleiades Publishing, Ltd., 2011.

Авторы
Romashkina E.P. 1 , Ilyukhin A.B.2 , Strashnova S.B. 1 , Koval'chukova O.V. 1 , Palkina K.K.2 , Sergienko V.S. 2 , Zaitsev B.E. 1
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
3
Язык
Английский
Страницы
350-356
Статус
Опубликовано
Подразделение
-
Номер
-
Том
56
Год
2011
Организации
  • 1 Peoples' Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 2 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russian Federation
Ключевые слова
Chlorine compounds; Cobalt compounds; Complexation; Copper compounds; Crystal structure; Crystalline materials; Metal ions; Metals; Molecular structure; Phenols; Potentiometers (electric measuring instruments); Samarium compounds; Ultraviolet visible spectroscopy; X ray diffraction; Complex compounds; Complexation process; Crystal and molecular structure; Crystalline state; Europium complex; IR and UV-Vis spectroscopies; Physicochemical methods; Stability constants; Europium compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2624/