Preparation of spiroaziridinefluorene, spiroindoxyl-fluorene, and Β-aminopropionic acid ester with a 4-azafluorene fragment

It has been established that the reaction of 9-(p-methoxyphenylimino)fluorene with dichlorocarbene (conditions of phase-transfer catalysis) proceeds in two directions - the formation of spiroaziridinefluorene and of spiroindoxylfluorene, the structure of which has been demonstrated. Opening of the aziridine ring of spiroaziridinefluorene has been accomplished. From the analagous azamethine, 4-aza-fluorene, an ester of N-substituted Β-aminopropionic acid with a 4-azafluorene fragment was obtained by alkylation of its dianion with methyl chloroacetate. © 1987 Plenum Publishing Corporation.

Авторы
Prostakov N.S. 1 , Gaivoronskaya L.A. 1 , Sarkar S.K.1 , Zakharov V.F. 1 , Durbazheva N.M.1
Редакторы
-
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
7
Язык
Английский
Страницы
710-713
Статус
Опубликовано
Подразделение
-
Номер
-
Том
22
Год
1986
Организации
  • 1 Patrice Lumumba Peoples' University, Moscow, 117293, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/1330/