Synthesis, structure, and magnetic properties of a copper(II) chloride complex with 3-amino-2-methyl-4H-pyrido[1,2-a]pyrimidin-4-one: The crystal structure Cu2Cl6(C9H10N3O)(2) center dot (C9H10N3O)Cl

The Complex Cu2Cl6(C9H10N3O)(2) . (C9H10N3O)Cl has been synthesized by the reaction between copper(II) chloride crystal hydrate and 3-amino-2-methyl-4H-pyrido[1,2-a]pyrimidin-4-one, and its crystal structure has been determined. The Cu2Cl6(C9H10N2O)(2) is a centrosymmetric dimer in which two copper atoms are linked by two bridging chlorine atoms. The hexachlorodicuprate anion contained in the dimer has a twice-folded conformation. The copper atom (CN = 5) coordinates two chlorine atoms and the amino-group nitrogen of the organic cation. An EPR study revealed the antiferromagnetic properties of the complex.

Authors
Kuz'mina N.E. , Palkina K.K. , Polyakova N.V. , Golubev I.N. , Medvedev A.N. , Koval'chukova O.V. , Strashnova S.B. , Mordovina N.I. , Nikitin S.V. , Zaitsev B.E.
Editors
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Publisher
IAPC Nauka/Interperiodica
Number of issue
2
Language
English
Pages
205-210
Status
Published
Department
-
Link
-
DOI
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Number
-
Volume
48
Year
2003
Organizations
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Keywords
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Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/8942/