Triarylazoimidazole-ZnII, CdII, and HgII Complexes: Structures, Photophysics, and Antibacterial Properties

Novel triarylazoimidazoles containing strong electron donors (p-NEt2) or acceptors (p-NO2) by the azoaryl group, and their group 12 metal complexes were synthesized and fully characterized, including X-ray analysis for several complexes. Novel complexes exhibit red photo-luminescence emission (Φ up to  0.21) in a solution. Moreover, the antibacterial activity of complexes was tested against Gram-positive microorganism S. aureus and Gram-negative microorganism.

Authors
Artemjev A.A. 1 , Astafiev A.A.2 , Vologzhanina A.V. 3 , Kubasov A.S.4 , Burkin G.M. 1 , Novikov A.S. 5 , Kritchenkov A.S. 1 , Kirichuk A.A. 1 , Tskhovrebov A.G. 1, 2
Journal
Crystals
Publisher
MDPI AG
Number of issue
5
Language
English
Pages
680-680
Status
Published
Volume
12
Year
2022
Organizations
  • 1 Peoples' Friendship University of Russia
  • 2 N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
  • 3 Institute of Organoelement Compounds of the Russian Academy of Sciences
  • 4 Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
  • 5 Saint-Petersburg State University
Keywords
azo dyes; nitrogen heterocycles; fluorescence; photoswitchable materials; Zn; Cd; Hg complexes; azoimidazoles
Date of creation
06.07.2022
Date of change
06.07.2022
Short link
https://repository.rudn.ru/en/records/article/record/86517/
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Article
Шестопалов А.Е., Яковлева А.В., Лукьянец О.Б., Петрова М.В.
Клиническое питание и метаболизм. Федеральный научно-клинический центр реаниматологии и реабилитологии, ООО "Эко-Вектор". Vol. 3. 2022. P. 38-49