Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers

Herein, we report the synthesis and characterizations of chiral copper(II) coordination polymers (CPs) based on Schiff base of (S)-2-aminomethylpyrrolidine and salicylaldehyde derivatives. Single crystal X-ray analysis showed that copper(II) complex is 1D CP, with the repeating units LCu-OAc (L=ligand) organized in a perpendicular manner, where the copper(II) atoms are six-coordinated and have a distorted octahedral geometry. Also complex with chlorine counter ion having unusual dimeric structure was synthesized and characterized. It was demonstrated that CPs catalyze the enantioselective Henry reaction with up to 78% ee. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Authors
Larionov V.A. 1, 2 , Yashkina L.V.1 , Smol'yakov A.F. 1 , Zubavichus Y.V.3 , Babievsky K.K.1 , Akat'yev N.V.1 , Titov A.A. 1 , Belokon Y.N.1 , Maleev V.I.1
Journal
ChemistrySelect
Publisher
Wiley-Blackwell
Number of issue
2
Language
English
Pages
653-656
Status
Published
Link
External link
DOI
10.1002/slct.201702689
Volume
3
Year
2018
Organizations
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, Moscow, 119991, Russian Federation
  • 2 Department of Inorganic Chemistry, People's Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya Street, Moscow, 117198, Russian Federation
  • 3 National Research Center ‘‘Kurchatov Institute'', 1 Akad. Kurchatova Sq., Moscow, 123098, Russian Federation
Keywords
Aldol reaction; Coordination polymers; Copper; N,O ligands; Tridentate ligands
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/7197/
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