Structure of Monomeric Octahedral d 2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands

The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.

Authors
Publisher
IAPC Nauka/Interperiodica
Number of issue
7
Language
English
Pages
882-885
Status
Published
Volume
64
Year
2019
Organizations
  • 1 Kurnakov Institute of General and Inorganic Chemistry|Russian Academy of Sciences
  • 2 All-Russia Institute for Scientific and Technical Information|Russian Academy of Sciences
  • 3 Peoples’ Friendship University of Russia
Keywords
4) (O; crystal structure; n-dentate (n = 3; O) and (O; O) ligands; six-coordinated d<sup>2</sup>-Re monooxo compounds; x-ray structural analysis
Date of creation
20.02.2020
Date of change
20.02.2020
Short link
https://repository.rudn.ru/en/records/article/record/60084/
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