Structure of Monomeric Octahedral d 2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands

Abstract: The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds. © 2019, Pleiades Publishing, Ltd.

Authors
Sergienko V.S. 1, 2 , Strashnova S.B. 3
Journal
Russian Journal of Inorganic Chemistry
Publisher
IAPC Nauka/Interperiodica
Number of issue
7
Language
English
Pages
882-885
Status
Published
Link
External link
DOI
10.1134/S0036023619070143
Volume
64
Year
2019
Organizations
  • 1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
  • 2 All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences, Moscow, 125190, Russian Federation
  • 3 Peoples’ Friendship University of Russia, Moscow, 117198, Russian Federation
Keywords
4) (O; : crystal structure; n-dentate (n = 3; O; O; O; O) and (O; O) ligands; six-coordinated d2-Re monooxo compounds; X-ray structural analysis
Date of creation
24.12.2019
Date of change
24.12.2019
Short link
https://repository.rudn.ru/en/records/article/record/55181/
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