First cage-like pentanuclear Co(II)-silsesquioxane

A new pentanuclear "cylinder"-like cobalt(ii) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols. © The Royal Society of Chemistry 2016.

Authors
Bilyachenko A.N. 1, 2 , Yalymov A.I.1 , Levitsky M.M.1 , Korlyukov A.A.1, 7 , Es'Kova M.A.1 , Long J.3 , Larionova J.3 , Guari Y.3 , Shul'Pina L.S.1 , Ikonnikov N.S.1 , Trigub A.L.4 , Zubavichus Y.V.4 , Golub I.E.1 , Shubina E.S.1 , Shul'Pin G.B.5, 6
Journal
Dalton Transactions
Publisher
Royal Society of Chemistry
Number of issue
35
Language
English
Pages
13663-13666
Status
Published
Link
External link
DOI
10.1039/c6dt02026g
Volume
45
Year
2016
Organizations
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilov str. 28, Moscow, Russian Federation
  • 2 People's Friendship University of Russia, Miklukho-Maklay Str. 6, Moscow, 117198, Russian Federation
  • 3 Institut Charles Gerhardt de Montpellier (ICGM), UMR5253, Equipe IMNO, Université de Montpellier, Site Triolet Place Eugène Bataillon, Montpellier Cedex 5, 34095, France
  • 4 National Research Center, Kurchatov Institute, pl. Akad. Kurchatova 1, Moscow, 123098, Russian Federation
  • 5 Semenov Institute of Chemical Physics of RAS, ul. Kosygina dom 4, Moscow, 119991, Russian Federation
  • 6 Plekhanov Russian University of Economics, Stremyannyi pereulok dom 36, Moscow, 117997, Russian Federation
  • 7 Pirogov Russian National Research Medical University, Moscow, 117997, Russian Federation
Keywords
Catalytic oxidation; Cobalt compounds; Cage likes; Oxidation of alkanes; Pentanuclear; Phenylsilsesquioxane; Silsesquioxanes; Slow relaxations; Catalyst activity
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/4453/
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