One-pot condensation of 2-arylpropenes with formaldehyde and ammonium chloride: The synthesis of aryl substituted pyridines and 5,7,11-trioxa-1-azatricyclo[7.3.1.03,8]tridecanes

A mixture consisting of 2-arylpropene 1 or 2, formaldehyde and ammonium chloride condenses in a one-pot manner to yield 5,7,11-trioxa-1-azatricyclo [7.3.1.03,8]tridecanes 3 or 4. In the presence of manganese dioxide the reaction leads to 4-arylpyridines 5 or 6.

Publisher
Royal Society of Chemistry
Number of issue
4
Language
English
Pages
154-155
Status
Published
Volume
11
Year
2001
Organizations
  • 1 Peoples' Friendship Univ. Russia, 117198 Moscow, Russian Federation
Keywords
5,7,11 trioxa 1 azatricyclo[7.3.1.0 3,8]tridecane derivative; propylene; pyridine derivative; unclassified drug; aromatization; article; chemical reaction; crystal structure; methylation; polymerization; proton nuclear magnetic resonance; reaction analysis; X ray analysis
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/354/
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