Effect of the nature of axial ligand on the effective charge of the metal center in PcFe(II) complexes

Disubstituted iron phthalocyanine complexes were studied by X-ray photoelectron spectroscopy (XPS). Fe2p 3/2, N1s, and C1s XPS spectra were analyzed, and the role of the ligand in their generation was determined. Assignment of the magnetic properties of phthalocyanine iron complexes was done. Covalence of the metal-ligand bond was determined. The nature of the axial ligand in PctFe affects the electronic state of the central iron atom. © 2008 Pleiades Publishing, Ltd.

Authors
Ivanova T.M. 1 , Linko R.V. 2 , Petrov A.V.3 , Bazanov M.I.3 , Dyumaev K.M.4
Journal
Russian Journal of Inorganic Chemistry
Publisher
IAPC Nauka/Interperiodica
Number of issue
11
Language
English
Pages
1784-1787
Status
Published
Link
External link
DOI
10.1134/S0036023608110193
Volume
53
Year
2008
Organizations
  • 1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russian Federation
  • 2 Russian University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 3 Ivanovo State University of Chemical Technology, pr. Engelsa 7, Ivanovo 153460, Russian Federation
  • 4 All-Russia Institute of Medicinal and Aromatic Plants, Moscow, Russian Federation
Keywords
Electronic states; Iron compounds; Ligands; Axial ligand; Effective charge; Iron atoms; Iron complex; Iron phthalocyanines; Metal centers; Metal-ligand bonds; XPS spectra; X ray photoelectron spectroscopy
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/3156/
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