Russian Journal of Inorganic Chemistry.
IAPC Nauka/Interperiodica.
Vol. 53.
2008.
P. 1227-1232
Spin-vibrational interactions in geminate radical pairs: Effective spin hamiltonian including anharmonicity
An equation for the effective spin Hamiltonian including the interaction of radical pair spins with vibrations in both linear and higher approximations was obtained. Even in the linear approximation, the Hamiltonian was found to be non-Heisenberg. The influence of a sound field on the probability of geminate radical pair recombination is considered in the Appendix. The results obtained can be of use for solving certain nanochemistry problems. © 2008 Pleiades Publishing, Ltd.
Authors
Kubarev S.I.1
,
Shigaev A.S.2
,
Kubareva I.S.
3
,
Ponomarev V.O.4
,
Ponomarev O.A.2
Number of issue
3
Language
English
Pages
329-342
Status
Published
Link
Volume
2
Year
2008
Organizations
- 1 Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 117977, Russian Federation
- 2 Institute of Cell Biophysics, Russian Academy of Sciences, Pushchino, Moscow oblast, 142292, Russian Federation
- 3 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
- 4 Moscow State Academy of Water Transport, Moscow, Russian Federation
Date of creation
19.10.2018
Date of change
19.10.2018
Share
Other records
Russian Journal of Inorganic Chemistry.
IAPC Nauka/Interperiodica.
Vol. 53.
2008.
P. 1784-1787