Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta-[c] pyridine-7-carboxylate ethanol solvate

The title compound, the product of an acid-catalysed Wagner-Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C 20H21NO8·C2H6O. The title mol-ecule comprises a fused tricyclic system containing two five-membered rings (cyclo-pentane and tetra-hydro-furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist-boat conformation.

Authors
Gurbanov A.V.1 , Nikitina E.V. 2 , Airiyan I.K. 2 , Zaytsev V.P. 2 , Khrustalev V.N.3
Journal
Acta Crystallographica Section E: Structure Reports Online
Number of issue
12
Language
English
Status
Published
Link
External link
DOI
10.1107/S1600536809045528
Volume
65
Year
2009
Organizations
  • 1 Baku State University, Z. Khalilov St 23, Baku, AZ-1148, Azerbaijan
  • 2 Organic Chemistry Department, Russian Peoples Friendship University, Miklukho-Maklaya St 6, Moscow 117198, Russian Federation
  • 3 X-Ray Structural Centre, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St B-334, Moscow 119991, Russian Federation
Keywords
Tetra
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/2849/
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