Synthesis and physicochemical study of hexaamminechromium(III) hexamolybdogallate

Hexaamminechromium(III) hexamolybdogallate of composition [Cr(NH 3)6][GaMo6O18(OH)6] • 5H2O (I) was synthesized and studied by mass spectrometry, IR spectroscopy, thermogravimetry, and X-ray diffraction. Crystals I are monoclinic: a = 11.77 Å, b = 10.97 Å, c = 15.49 Å, β = 115.11°, V = 1811.29 Å3, ρcalc = 1.17 g/cm3, Z = 1. The compound obtained was used as a catalyst for soft oxidation of natural gas at 633 K. © 2011 Pleiades Publishing, Ltd.

Authors
Oreshkina A.V.1 , Kaziev G.Z.1 , Lobanov N.N. 2 , Shipilova P.A.1
Publisher
IAPC Nauka/Interperiodica
Number of issue
11
Language
English
Pages
1698-1701
Status
Published
Volume
56
Year
2011
Organizations
  • 1 Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1, Moscow 119991, Russian Federation
  • 2 Peoples Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Keywords
Mass spectrometry; Thermogravimetric analysis; Physicochemical studies; X ray diffraction
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/2614/
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