Reversible activated adsorption of gases on metals

It was experimentally shown that, along with ordinary adsorption, the H2-Rh, CO-Rh, Co-Ni, C2H4-Ni, n-C6H14-Ni, CO-Ta, and H2-Ta systems exhibited reversible activated adsorption. A thermodynamic model of reversible activated adsorption of gases was proposed. According to this model, mobile metal adatoms were involved in the formation of new adsorption sites, whose number increased with temperature.

Редакторы
-
Издательство
-
Номер выпуска
1
Язык
Английский
Страницы
77-82
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
77
Год
2003
Организации
  • 1 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Ключевые слова
carbon monoxide; hydrogen; metal; nickel; rhenium; rhodium; tantalum; accuracy; adsorption; article; chemical binding; entropy; gas; model; temperature dependence; thermodynamics
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/96/