Synthesis, structure, and magnetic properties of a copper(II) chloride complex with 3-amino-2-methyl-4H-pyrido[1,2-a]pyrimidin-4-one: The crystal structure Cu2Cl6(C9H10N3O)(2) center dot (C9H10N3O)Cl

The Complex Cu2Cl6(C9H10N3O)(2) . (C9H10N3O)Cl has been synthesized by the reaction between copper(II) chloride crystal hydrate and 3-amino-2-methyl-4H-pyrido[1,2-a]pyrimidin-4-one, and its crystal structure has been determined. The Cu2Cl6(C9H10N2O)(2) is a centrosymmetric dimer in which two copper atoms are linked by two bridging chlorine atoms. The hexachlorodicuprate anion contained in the dimer has a twice-folded conformation. The copper atom (CN = 5) coordinates two chlorine atoms and the amino-group nitrogen of the organic cation. An EPR study revealed the antiferromagnetic properties of the complex.

Авторы
Kuz'mina N.E. , Palkina K.K. , Polyakova N.V. , Golubev I.N. , Medvedev A.N. , Koval'chukova O.V. , Strashnova S.B. , Mordovina N.I. , Nikitin S.V. , Zaitsev B.E.
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
2
Язык
Английский
Страницы
205-210
Статус
Опубликовано
Подразделение
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Ссылка
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DOI
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Номер
-
Том
48
Год
2003
Организации
-
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/8942/