Synthesis and Physicochemical Properties of Chromium(III) and Iron(III) Complexes with Bromonitrofluorenones

Polynuclear complexes [M3O(CH3COO)6(H2O)2L]OH and Fe2O(CH3COO)4L2 2 (H2O)2, where M = Cr(III), Fe(III); L = 5-bromo-2,4,7-trinitrofluorenone (L1) and 4,5-dibromo-2,7-dinitrofluorenone (L2), were synthesized. Quantum-chemical calculation of the electronic structure and spectra of 5-chloro-2,4,7-trinitrofluorenone was performed by the Pariser-Parr-Pople method. IR and electronic absorption spectra indicate that bromonitrofluorenones are incorporated into trinuclear (μ-oxo)acetato complexes as neutral terminal ligands coordinated through the carbonyl oxygen.

Авторы
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
7
Язык
Английский
Страницы
1094-1097
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
41
Год
1996
Организации
  • 1 University of Peoples's Friendship, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/858/