Influence of Temperature on Complex Formation of Metal with Aminophenanthridones

Color change of manganese(II), iron(III), cobalt(II), nickel(II), copper(II), chromium(III), and zinc(II) complexes with aminophenanthridones at 50-180°C is observed. The peculiarities of this effect, the reaction order, the reaction rate constant, and the activation energy are studied. Color change is explained by the rearrangement of the electronic structure of the complex and is assumed to be due to an increase in the contribution of the bipolar form of the ligand.

Авторы
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
10
Язык
Английский
Страницы
1596-1602
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
41
Год
1996
Организации
  • 1 University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow GSP, 117198, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/842/