Methacrylate-Containing Phosphazene Oligomers

Abstract: Methacrylate-containing phosphazene oligomers are synthesized by the reaction of phosphazene-containing epoxy compounds with methacrylic acid and characterized by 1Н and 31Р NMR spectroscopy, MALDI-TOF mass spectrometry, and functional analysis. Methacrylate-containing phosphazene oligomers with the addition of 0.5% hydroquinone are stable under storage at normal temperature for 2 to 3 weeks but are easily involved in benzoyl peroxide-initiated copolymerization with methyl acrylate to give rise to copolymers with the quantitative content of the gel fraction. © 2022, Pleiades Publishing, Ltd.

Авторы
Sirotin I.S.1 , Son V.X.1 , Bilichenko Y.V.1 , Borisov R.S. 1, 2, 3 , Gorbunova E.A.1 , Kireev V.V.1
Журнал
Polymer Science - Series B
Издательство
Pleiades Publishing
Номер выпуска
2
Язык
Английский
Страницы
109-116
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1134/S1560090422020129
Том
64
Год
2022
Организации
  • 1 Mendeleev University of Chemical Technology, Moscow, 125047, Russian Federation
  • 2 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russian Federation
  • 3 Peoples’ Friendship University of Russia, Moscow, 117198, Russian Federation
Ключевые слова
Benzoyl peroxide; Mass spectrometry; Nuclear magnetic resonance spectroscopy; Copolymerisation; Epoxy compound; Gel fraction; MALDI-TOF mass spectrometry; Methacrylic acids; Methyl acrylates; NMR-spectroscopy; Phosphazenes; Synthesised; Oligomers
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