2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior

Reactions of Zn(II) nitrate, 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine (ThioTerPy) and terephtalic (bdc) or 2-iodoterephtalic (2-I-bdc) acids result in 2D coordination polymer [Zn2bdc(ThioTerPy)2(OH)2] (1) or 3D metal-organic framework [Zn(2-I-bdc)(ThioTerPy)] (2), respectively. Both compounds were characterized by X-ray diffractometry. For 2, I2 absorption, as well as selectivity of sorption of different organic substrates from mixtures was studied. © 2022 Elsevier B.V.

Авторы
Zaguzin A.S.1, 2 , Mahmoudi G. 3 , Sukhikh T.S.2 , Sakhapov I.F.1, 4 , Zherebtsov D.A.1 , Zubkov F.I. 5 , Valchuk K.S. 5 , Sokolov M.N.2 , Fedin V.P.2 , Adonin S.A.1, 2
Язык
Английский
Статус
Опубликовано
Номер
132459
Том
1255
Год
2022
Организации
  • 1 South Ural State University, Chelyabinsk, 454080, Russian Federation
  • 2 Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation
  • 3 Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, Iran
  • 4 Arbuzov Institute of Organic and Physical Chemistry RAS, Kazan, Russian Federation
  • 5 Organic Chemistry Department, Faculty of Science, Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
Ключевые слова
Iodine absorption; Metal-organic frameworks; N-donor ligands; Polypyridyls
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