Chemically functionalized MIL-101-NH2 with cobalt(II) tetrasulfophthalocyanine: an efficient catalyst for the aerobic oxidation of alcohols and one-pot tandem conversion of alcohols to propargylamines

In this investigation, MIL-101-NH2 chemically functionalized with cobalt(II) tetrasulfophthalocyanine (CoTSPc) through a superior electrostatic interaction reaction. The configuration of the synthesized composite was characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermal gravimetric analysis (TGA), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscope (SEM), and inductively coupled plasma optical emission spectrometer (ICP-OES). This spongy composite showed excellent catalytic activity in the aerobic oxidation reaction of primary and secondary benzylic alcohols. The generated catalyst's behavior was examined to synthesize propargylamines via tandem oxidative A3 coupling process to illustrate the maximum potential of the synthesized catalyst. Utilizing air as an oxidant, operational simplicity, easy preparation, apt yielding, non‐hazardous nature of the catalyst, and reusability are the essential advantages of this catalyst. © 2021 Taiwan Institute of Chemical Engineers

Авторы
Shaabani A. 1, 2 , Amini M.M.3 , Shadi M.1 , Bahri F.1 , Alavijeh M.K.3 , Farhid H.1
Издательство
Taiwan Institute of Chemical Engineers
Язык
Английский
Страницы
211-222
Статус
Опубликовано
Том
126
Год
2021
Организации
  • 1 Department of Organic Chemistry, Faculty of Chemistry, Shahid Beheshti University, Tehran, 1983969411, Iran
  • 2 Рeoples’ Friendship University of Russia (RUDN University), 6, Miklukho-Maklaya Street, Moscow, 117198, Russian Federation
  • 3 Department of Inorganic Chemistry and Catalysis, Faculty of Chemistry, Shahid Beheshti University, Tehran, 1983969411, Iran
Ключевые слова
A3 coupling reaction; Aerobic oxidation reaction; Heterogeneous catalyst; Metallophthalocyanines; Metal–organic framework; Tandem oxidation process
Дата создания
16.12.2021
Дата изменения
16.12.2021
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/76680/
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