Crystal structure and Hirshfeld surface analysis of 4,5-dibromo-6-methyl-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-3a,6-epoxy-1H-isoindol-1-one

In the title compound, C15H15Br2NO2, two bridged tetrahydrofuran rings adopt envelope conformations with the O atom as the flap. The pyrrolidine ring also adopts an envelope conformation with the spiro C atom as the flap. In the crystal, the molecules are linked into dimers by pairs of C - H⋯O hydrogen bonds, thus generating R22(18) rings. The crystal packing is dominated by H⋯H, Br⋯H, H⋯π and Br⋯π interactions. One of the Br atoms is disordered over two sites with occupation ratio of 0.833 (8):0.167 (8). © 2021.

Авторы
Mertsalov D.F. 1 , Nadirova M.A. 1 , Chervyakova L.V. 1 , Grigoriev M.S.2 , Shelukho E.R. 1 , Çelikesir S.T.3 , Akkurt M.3 , Mlowe S.4
Издательство
International Union of Crystallography
Язык
Английский
Страницы
237-241
Статус
Опубликовано
Том
77
Год
2021
Организации
  • 1 Department of Organic Chemistry, Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 2 Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky pr. 31, bld. 4, Moscow, 119071, Russian Federation
  • 3 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 4 University of Dar es Salaam, Dar es Salaam University College of Education, Department of Chemistry, PO Box 2329, Dar es Salaam, Tanzania
Ключевые слова
crystal structure; epoxyisoindole moiety; Hirshfeld surface analysis; pyrrolidine ring; tetrahydrofuran ring
Дата создания
20.07.2021
Дата изменения
20.07.2021
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/74116/
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