New Ni4Na2-phenylgermsesquioxane architecture: Synthesis, structure and slow dynamic behaviour

The first Ni(ii)-based metallagermaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a sandwich-like structure where two germsesquioxane cages are linked through an {NiO}4 core and exhibits slow dynamics of the magnetization. © 2018 The Royal Society of Chemistry.

Авторы
Kulakova A.N. 1, 2, 3 , Bilyachenko A.N. 1, 2 , Korlyukov A.A. 1, 4 , Long J. 3 , Levitsky M.M. 1 , Shubina E.S. 1 , Guari Y. 3 , Larionova J. 3
Журнал
Dalton Transactions
Издательство
Royal Society of Chemistry
Номер выпуска
20
Язык
Английский
Страницы
6893-6897
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1039/C8DT00900G
Том
47
Год
2018
Организации
  • 1 A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklay Street 6, Moscow, 117198, Russian Federation
  • 3 Institut Charles Gerhardt, UMR5253, University of Montpellier, ENSCM, CNRS, Pl. Eugène Bataillon, Montpellier cedex 05, 34095, France
  • 4 Pirogov Russian National Research Medical University, Ostrovitianov str. 1, Moscow, 117997, Russian Federation
Ключевые слова
Chemistry; Inorganic compounds; Cage compounds; Sandwich-like structure; Slow dynamics; Nickel oxide
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