Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic). © 2018 The Royal Society of Chemistry.

Авторы
Arzumanyan A.V.1 , Goncharova I.K.1 , Novikov R.A.2 , Milenin S.A.3 , Boldyrev K.L.3 , Solyev P.N.2 , Tkachev Y.V.2 , Volodin A.D.1 , Smol'Yakov A.F. 1, 4 , Korlyukov A.A. 1, 5 , Muzafarov A.M.1, 3
Редакторы
-
Журнал
Издательство
Royal Society of Chemistry
Номер выпуска
7
Язык
Английский
Страницы
1467-1471
Статус
Опубликовано
Подразделение
-
Номер
-
Том
20
Год
2018
Организации
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, 119991, Russian Federation
  • 2 Engelhardt Institute of Molecular Biology, Russian Academy of Sciences, 32 Vavilova St., Moscow, 119991, Russian Federation
  • 3 Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 Profsoyuznaya St., Moscow, 117393, Russian Federation
  • 4 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 5 N.I. Pirogov Russian National Research Medical University, 1 Ostrovityanov St., Moscow, 117997, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/7372/