Intensification of butane dehydrogenation on a granular catalyst by hydrogen removal through palladium alloy membranes

A commercial Cr2O3-Al2O3 catalyst was placed in one of two zones of a plug flow reactor with a palladium alloy membrane. The oxidation of hydrogen diffusing from the zone of butane dehydrogenation gave higher butadiene yields than hydrogen removal by an argon flow. The magnitude of the effect depended on the nature and content of the second palladium alloy component. The most efficient membrane for the synthesis of butene and butadiene from butane was a palladium-tin alloy.

Авторы
Orekhova N.V.1 , Ermilova M.M.1 , Gryaznov V.M. 2
Редакторы
-
Издательство
-
Номер выпуска
9
Язык
Английский
Страницы
1389-1392
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
71
Год
1997
Организации
  • 1 Topchiev Inst. Petrochem. Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 117912, Russian Federation
  • 2 Russ. Univ. of People's Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/726/