Catalytic Transfer Hydrogenation Using Biomass as Hydrogen Source

We developed an operationally simple method for the direct use of biomass-derived chemical entities in a fundamentally important process, such as hydrogenation. Various carbohydrates, starch, and lignin were used for stereoselective hydrogenation. Employing a transition metal catalyst and a novel catalytic system, the reduction of alkynes, alkenes, and carbonyl groups with high yields was demonstrated. The regioselective hydrogenation to access different stereoisomers was established by simple variations in the reaction conditions. This work is based on an unprecedented catalytic system and represents a straightforward application of biomass as a reducing reagent in chemical reactions. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Авторы
Manna S.1, 2 , Antonchick A.P. 1, 2, 3
Журнал
Издательство
Wiley-VCH Verlag
Язык
Английский
Статус
Опубликовано
Год
2018
Организации
  • 1 Abteilung Chemische Biologie, Max-Planck-Institut für Molekulare Physiologie, Otto-Hahn-Strasse 11, Dortmund, 44227, Germany
  • 2 Fakultät Chemie and Chemische Biologie, Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 4a, Dortmund, 44227, Germany
  • 3 Faculty of Science, Peoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian Federation
Ключевые слова
biomass; carbohydrates; green chemistry; hydrogenation; rhodium
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/7257/