Ruthenium-Catalyzed Reductive Amidation without an External Hydrogen Source

A catalytic reaction between aldehydes and primary amides that leads to N-alkylated amides was investigated. The developed protocol employs carbon monoxide as a deoxygenative agent and, therefore, avoids the use of an external hydrogen source. Cyclopentadienyl ruthenium complexes provided excellent catalytic efficiency and could be used with loadings as low as 0.5–1 mol-%. A representative number of secondary amides were successfully prepared in yields of 70–84 %. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Авторы
Yagafarov N.Z. 1 , Muratov K.M.1 , Biriukov K.1 , Usanov D.L.2 , Chusova O. 3 , Perekalin D.S. 1 , Chusov D. 1, 3
Номер выпуска
4
Язык
Английский
Страницы
557-563
Статус
Опубликовано
Том
2018
Год
2018
Организации
  • 1 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
  • 2 Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
  • 3 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
Ключевые слова
Aldehydes; Amides; Homogeneous catalysis; Reductive amidation; Ruthenium
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/6890/
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Другие записи

Konovalov A.I., Antipin I.S., Burilov V.A., Madzhidov T.I., Kurbangalieva A.R., Nemtarev A.V., Solovieva S.E., Stoikov I.I., Mamedov V.A., Zakharova L.Y., Gavrilova E.L., Sinyashin O.G., Balova I.A., Vasilyev A.V., Zenkevich I.G., Krasavin M.Y., Kuznetsov M.A., Molchanov A.P., Novikov M.S., Nikolaev V.A., Rodina L.L., Khlebnikov A.F., Beletskaya I.P., Vatsadze S.Z., Gromov S.P., Zyk N.V., Lebedev A.T., Lemenovskii D.A., Petrosyan V.S., Nenaidenko V.G., Negrebetskii V.V., Baukov Y.I., Shmigol’ T.A., Korlyukov A.A., Tikhomirov A.S., Shchekotikhin A.E., Traven’ V.F., Voskresenskii L.G., Zubkov F.I., Golubchikov O.A., Semeikin A.S., Berezin D.B., Stuzhin P.A., Filimonov V.D., Krasnokutskaya E.A., Fedorov A.Y., Nyuchev A.V., Orlov V.Y., Begunov R.S., Rusakov A.I., Kolobov A.V., Kofanov E.R., Fedotova O.V., Egorova A.Y., Charushin V.N., Chupakhin O.N., Klimochkin Y.N., Osyanin V.A., Reznikov A.N., Fisyuk A.S., Sagitullina G.P., Aksenov A.V., Aksenov N.A., Grachev M.K., Maslennikova V.I., Koroteev M.P., Brel’ A.K., Lisina S.V., Medvedeva S.M., Shikhaliev K.S., Suboch G.A., Tovbis M.S., Mironovich L.M., Ivanov S.M., Kurbatov S.V., Kletskii M.E., Burov O.N., Kobrakov K.I., Kuznetsov D.N.
Russian Journal of Organic Chemistry. Том 54. 2018. С. 157-371