Reactions of 4,4,9-trimethyl-4,9-dihydro-4-silanaphtho[3,2-b]thiophen-9-one with nucleophilic and electrophilic reagents

We have studied the reaction of 4,4,9-trimethyl-4,9-dihydro-4-silanaphtho[3,2-b]-thiophen-9-one with organometallic compounds, lithium aluminum hydride, sodium borohydride, aniline, and acetyl nitrate. We have obtained secondary and tertiary dihydrosilanaphtho[3,2-b]thiophen-9-ols and 9-phenyliminodihydrosilanaphtho[3,2-b]thiophene. We have established that nitration of dihydrosilanaphthothiophen-9-one occurs at the α position of the thiophene moiety. ©1998 Plenum Publishing Corporation.

Авторы
Varlamov A.V. 1 , Astakhov A.A.1 , Akoto L.1 , Golovtsov N.I. 1 , Chernyshev A.V.1
Редакторы
-
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
5
Язык
Английский
Страницы
545-549
Статус
Опубликовано
Подразделение
-
Номер
-
Том
34
Год
1998
Организации
  • 1 Russian University of International Friendship, Moscow 117923, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/680/