Oxidation reactions of azines. 10. Synthesis, structure, and oxodihydroxylation of 3-hydroxymethyl-1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine

It has been established that oxidation of a mixture of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine and dicyanomethane or formaldehyde with manganese dioxide gives 3-hydroxymethyl-1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine, the structure of which was confirmed by X-ray structural analysis. Some oxidative conversions by potassium permanganate of the product formed and its esters have been studied. These included lactamization, aromatization, and oxodihydroxylation.

Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
4
Язык
Английский
Страницы
471-477
Статус
Опубликовано
Том
39
Год
2003
Организации
  • 1 Russ. People's Friendship University, Moscow 117198, Russian Federation
Ключевые слова
Hydroxymethylation; Oxidation; Oxodihydroxylation; Polyhydroxypiperidin-2-ones; Tetrahydropyridines
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/68/