Unusual Transformations of Cyclic Allenes with an Enamine Moiety into Complex Frameworks

The thermolysis reactions of benzoazacyclodecatrienes under microwave irradiation conditions in toluene at 150 °C afforded complex azabenzo[ a ]cyclopropa[ cd ]azulene and (epiminomethano)cyclopenta[ a ]indene frameworks. Cyclopropanes were established as intermediates of the ultimate thermolysis products. © 2020 Georg Thieme Verlag. All rights reserved.

Авторы
Titov A.A. 1 , Kobzev M.S. 1 , Borisova T.N. 1 , Sorokina E.A. 1 , Van Der Eycken E. , Varlamov A.V. 1 , Voskressensky L.G. 1
Журнал
Synlett
Номер выпуска
7
Язык
Английский
Страницы
672-676
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1055/S-0039-1691586
Том
31
Год
2020
Организации
  • 1 Organic Chemistry Department, Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation
  • 2 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven (KU Leuven), Celestijnenlaan 200F, Leuven, 3001, Belgium
Ключевые слова
azacyclic allene; cyclopropanes; epiminomethanocyclopentaindenes; microwave-assisted reaction; polyheterocyclic compounds; thermal transformation
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