Tridecanuclear CuII 11Na2 Cagelike Silsesquioxanes

A series of three unprecedented heterometallic copper(II) sodium silsesquioxanes were isolated (i) via the unusual rearrangement process during synthesis of coordination polymers or (ii) via the self-assembly reaction using 2,2′-bipyridine. The unique type of these products' molecular topology consists of an unusual fusion of two sandwich-like components (each including five copper and one sodium sites) via a central copper ion. These compounds correspond to the highest nuclearity among Cu(II)-based cage silsesquioxanes reported to date. Copyright © 2018 American Chemical Society.

Авторы
Astakhov G.S. 1, 2 , Bilyachenko A.N. 1, 2 , Levitsky M.M.1 , Korlyukov A.A. 2, 3 , Zubavichus Y.V.4 , Dorovatovskii P.V.4 , Khrustalev V.N. 2, 4 , Vologzhanina A.V.1 , Shubina E.S.1
Редакторы
-
Издательство
American Chemical Society
Номер выпуска
9
Язык
Английский
Страницы
5377-5384
Статус
Опубликовано
Подразделение
-
Номер
-
Том
18
Год
2018
Организации
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str., 28, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University of Russia, Miklukho-Maklay Str., 6, Moscow, 117198, Russian Federation
  • 3 Pirogov Russian National Research Medical University, Ostrovitianov str., 1, Moscow, 117997, Russian Federation
  • 4 National Research Center, Kurchatov Institute, Akademika Kurchatova pl., 1, Moscow, 123182, Russian Federation
Ключевые слова
Coordination reactions; Metal ions; Self assembly; 2 ,2'-Bipyridine; Coordination Polymers; Copper ions; Heterometallics; Molecular topologies; Rearrangement process; Self-assembly reactions; Silsesquioxanes; Copper compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/6423/