Espacios.
Revista Espacios.
Том 38.
2017.
Direct C-2 acylation of indoles with toluene derivatives via Pd(II)-catalyzed C-H activation
A simple and efficient Pd-catalyzed method for the C2-acylation of indoles is described. Less toxic, stable, and commercially available toluene derivatives were used as acyl sources, with tert-butylhydroperoxide (TBHP) as oxidant and pivalic acid as additive, providing moderate to good yields. © 2017 The Royal Society of Chemistry.
Авторы
Zhao Y.3
,
Sharma U.K.1
,
Schröder F.1
,
Sharma N.1
,
Song G.3
,
Van Der Eycken E.V.
Журнал
Номер выпуска
52
Язык
Английский
Страницы
32559-32563
Статус
Опубликовано
Ссылка
Том
7
Год
2017
Организации
- 1 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven, KU Leuven, Celestijnenlaan 200F, Leuven, B-3001, Belgium
- 2 Peoples Friendship University of Russia, RUDN University, 6 Miklukho-Maklaya street, Moscow, 117198, Russian Federation
- 3 Shanghai Key Laboratory of Chemical Biology, East China University of Science and Technology, Shanghai, 200237, China
Ключевые слова
Activation analysis; Acylation; Catalysis; Toluene; Acyl source; C-h activation; Pivalic acid; Tert-butylhydroperoxide; Palladium compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
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