Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal−π interactions

The interaction of copper(I) and silver(I) macrocyclic pyrazolates with aromatic ligands of ruthenium sandwiches (Cp*RuInd, CpRuInd, and Ind2Ru) in solution is shown for the first time. The similar mode of coordination of macrocycles to the C6 fragment of indenyl ligand was found both in the solution and in the solid state. Complexation of macrocycles with the nonencumbered sandwiches (CpRuInd, Ind2Ru) leads to the formation of infinite stacks via alternating molecules of macrocycles and sandwich compounds as one-dimensional coordination polymers with a regular structure. Coordination mode of the indenyl ligand is independent of the second part of the ruthenium sandwich as well as of the aromatic ligand coordinated to another face of the macrocycle. The general principle of macrocycle supramolecular packing suggests coordination of two ligands on both faces of the macrocycle. © 2017 American Chemical Society.

Авторы
Titov A.A. 1, 2 , Smol’yakov A.F. 1, 2 , Filippov O.A.1 , Godovikov I.A.1 , Muratov D.A.1 , Dolgushin F.M.1 , Epstein L.M.1 , Shubina E.S.1
Редакторы
-
Издательство
American Chemical Society
Номер выпуска
12
Язык
Английский
Страницы
6770-6779
Статус
Опубликовано
Подразделение
-
Номер
-
Том
17
Год
2017
Организации
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, INEOS RAS, Vavilova str. 28, Moscow, 119991, Russian Federation
  • 2 Peoples’ Friendship University of Russia, Miklukho-Maklaya str. 6, Moscow, 117198, Russian Federation
Ключевые слова
Aromatic compounds; Ligands; Ruthenium compounds; Silver compounds; Supramolecular chemistry; Aromatic ligands; Coordination modes; Indenyl ligands; One-dimensional coordination polymer; Pi interactions; Regular structure; Ruthenium sandwich compounds; Supramolecular packing; Copper compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/5955/