Transition-Metal Complexes of 4-Amino- and 4,6-Dihalopyrimidinoanthrones

Manganese(II), iron(III), cobalt(II), nickel(II), copper(II), zinc, and palladium(II) complexes of 4-amino-, 4-anilino-, 4-chloro-6-bromo-, and 4,6-dibromopyrimidinoanthrones were synthesized and isolated. As evident from infrared and electronic absorption spectroscopic data and the results of quantum-chemical calculations, the ligands coordinate to metal cations through the carbonyl oxygen atom and a ring nitrogen atom, unlike 2-amino derivatives of pyrimidinoanthrone (PA), which coordinate through a ring nitrogen atom only.

Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
8
Язык
Английский
Страницы
1248-1252
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
44
Год
1999
Организации
  • 1 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/572/