Reactions of Copper(II) Chloride with 1-(3,3-Dimethyl-3,4-Dihydroisoquinolin-1-yl)-1-(Quinolin-2-yl)Methane (L1): The Crystal Structure of the Reaction Product [ClCu(L1*=L1*)CuCl]

(3,3-Dimethyl-3,4-dihydroisoquinolin-1-yl)(quinolin-2-yl)methane (L1) was studied by spectroscopy (IR, 1H NMR, UV/Vis) in the solid state and in solutions. X-ray diffraction analysis showed that the final product of the reaction of CuCl2 with L1 is the binuclear complex [ClCu(L1*=L1*)CuCl] (I), in which the tetradentate bridging-chelating ligand joins two CuCl fragments through four nitrogen atoms, thus closing two six-membered metal-containing rings. The coordination polyhedron of the Cu(I) atom is a distorted triangle (Cu-N 1.99 and 2.09, Cu-Cl 2.115 Å). The possible mechanism of the formation of I in the reaction of CuCl2 with L1 is discussed.

Авторы
Sokol V.I.1 , Davydov V.V. 2 , Balebanova E.V. 2 , Elekhina N.A. 2 , Shklyaev Yu.V.3 , Sergienko V.S.1
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
3
Язык
Английский
Страницы
354-360
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
45
Год
2000
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 People's Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/482/