1-Morpholino-3,3-dimethyl-3,4-dihydroisoquinoline Complex with Copper(II) Nitrate

The complex (LH)2[Cu(NO3)4], where L is 1-morpholino-3,3-dimethyl-3,4-dihydroisoquinoline, is synthesized and characterized by X-ray crystallography and IR and electronic spectroscopy. The complex has a cationic-anionic structure. The organic ligand is protonated at the nitrogen atom of the dihydroisoquinoline moiety. The LH+ cations and [Cu(NO3)4]2- anions are linked by N-H⋯O hydrogen bonds. Of the four nitrato groups, one is coordinated monodentate, one is bidentate, and two are anisobidentate.

Авторы
Sokol V.I.1 , Ryabov M.A. 2 , MerkuR'eva N.Yu. 2 , Sergienko V.S.1 , Davydov V.V. 2 , Shklyaev Yu.V.3
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
12
Язык
Английский
Страницы
1834-1840
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
45
Год
2000
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/480/